Controlling and self assembling of monodisperse platinum nanocubes as efficient methanol oxidation electrocatalysts.
نویسندگان
چکیده
An efficient synthetic approach that enables not only the control of Pt nanocubes but also the one-pot fabrication of novel Pt nanocube assemblies was developed for the first time. The integration of well-defined building blocks and unique superstructures endows Pt nanocube assemblies with enhanced performance in the methanol electrooxidation, showing a new concept for further enhancing the performance of these catalysts.
منابع مشابه
Self-supported Pt nanoclusters via galvanic replacement from Cu2O nanocubes as efficient electrocatalysts.
A novel synthesis method for self-supported Pt nanoclusters (Pt NCs) comprised of interconnected 2-3 nm Pt nanoparticles was developed by employing the galvanic replacement process between Cu2O nanocubes and PtCl4(2-) ions. This discovered synthesis procedure eliminates the use of any polymer capping agents and enables a catalytically clean Pt surface. It is determined that the presence of H(+)...
متن کاملHighly active and durable methanol oxidation electrocatalyst based on the synergy of platinum-nickel hydroxide-graphene.
Active and durable electrocatalysts for methanol oxidation reaction are of critical importance to the commercial viability of direct methanol fuel cell technology. Unfortunately, current methanol oxidation electrocatalysts fall far short of expectations and suffer from rapid activity degradation. Here we report platinum-nickel hydroxide-graphene ternary hybrids as a possible solution to this lo...
متن کاملMonodispersed platinum nanocubes for enhanced electrocatalytic properties in alcohol electrooxidation.
We report Pt nanocubes of ∼4.5 nm in size synthesized by thermal decomposition in the presence of PVP. The Pt cubic electrocatalysts with dominantly exposed {100} facets show much improved electrocatalytic activities in methanol, ethanol and formic acid electrooxidation.
متن کاملSelf-assembled platinum nanoparticles on sulfonic acid-grafted graphene as effective electrocatalysts for methanol oxidation in direct methanol fuel cells
In this article, sulfonic acid-grafted reduced graphene oxide (S-rGO) were synthesized using a one-pot method under mild conditions, and used as Pt catalyst supports to prepare Pt/S-rGO electrocatalysts through a self-assembly route. The structure, morphologies and physicochemical properties of S-rGO were examined in detail by techniques such as atomic force microscope (AFM), transmission elect...
متن کاملSynthesis of monodisperse Pt nanocubes and their enhanced catalysis for oxygen reduction.
Synthesis of platinum (Pt) nanoparticles with controlled sizes and shapes is one of the most attractive goals in developing highly active Pt catalysts for fine chemical synthesis.1 Well-dispersed Pt nanoparticles are also an important catalyst for fuel cell reactions: they catalyze hydrogen (or alcohol) oxidation at an anode and oxygen reduction at a cathode.2 Pt nanoparticles are commonly prep...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 51 17 شماره
صفحات -
تاریخ انتشار 2015